có hàm Select đó bạn

theo bài

https://stackoverflow.com/questions/1442360/c-sharp-how-do-i-select-a-word-in-a-textbox-by-cursor-location

code

int cursorPosition = textBox1.SelectionStart;
int nextSpace = textBox1.Text.IndexOf(' ', cursorPosition);
int selectionStart = 0;
string trimmedString = string.Empty;
// Strip everything after the next space...
if (nextSpace != -1)
{
    trimmedString = textBox1.Text.Substring(0, nextSpace);
}
else
{
    trimmedString = textBox1.Text;
}


if (trimmedString.LastIndexOf(' ') != -1)
{
    selectionStart = 1 + trimmedString.LastIndexOf(' ');
    trimmedString = trimmedString.Substring(1 + trimmedString.LastIndexOf(' '));
}

textBox1.SelectionStart = selectionStart;
textBox1.SelectionLength = trimmedString.Length;